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AUTHOR(S): Vahobjon Kh. Sabirov
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ABSTRACT The citrate salt of methylene blue), (Mb)(H3Cit) 0.18H2O (where Mb =methylene blue cation and Cit = citrate anion)have been determined by single-crystal X-ray diffraction. MB+cation are is planar and stacked in an antiparallel fashion, exhibiting π–πassociations at a distance of 3.746(6)Å. The Mb+ cation forms a short contacts of the type C-H..O with citric anion through methyl groups of the NMe2 side substituents. Water molecules occupy voids between stacks of MB+ cations with a very low site occupancies and do not form any short contacts with the citric anion.The intermolecular interactionsand specific weak contacts were analyzed by Hirshfeld surface calculations. |
KEYWORDS methylene blue; citrate; a single crystal X-ray diffraction; π–πstacking; Hirshfeld surface calculation |
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Cite this paper Vahobjon Kh. Sabirov. (2022) Crystal Structure of Methylene Blue Citrate. International Journal of Biochemistry Research, 7, 1-9 |
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